Incoming boss Skinner told the club website: “I am really excited to be joining Tottenham Hotspur and cannot wait to get started in the WSL after the international break.
“The club’s philosophy and future plans are something I was really keen to be a part of.
“There is some incredible experience within this squad and I am looking forward to getting to work with the players so we can build on the progress that has been made so far and bring future success to the team.”
Skinner previously coached Great Britain at the World University Games, winning gold in 2013.
Spurs’ head of women’s football, Heather Cowan, added: “Rehanne has extensive experience in the women’s game and we are looking forward to having her with us now as we look to continue our journey forward in the WSL.”
Kay Cossington, the FA’s head of women’s technical development, told the FA website: “I am delighted for Rehanne. While we are sorry to see her leave, we are committed to helping our talented coaches progress in the game.
“This is a brilliant opportunity and I am sure England teams will feel the benefit in the future of having another WSL head coach who understands our commitment to furthering the player pathway.
“Meanwhile, it will open up another opportunity for a coach to join Phil’s coaching staff and work around the senior environment.”